Tetrachloridobis(dibenzyl sulfoxide-κO)tin(IV)
نویسندگان
چکیده
The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa-hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl⋯S = 3.320 (1) and 3.376 (1) Å]; the Sn-Cl bonds involving these two Cl atoms are longer than the other two Sn-Cl bonds.
منابع مشابه
Bis(dimethyl sulfoxide-κO)bis(mercaptoacetato-κ2 O,S)tin(IV)
In the title compound, [Sn(C(2)H(2)O(2)S)(2)(C(2)H(6)OS)(2)], the mercaptoacetato ligands chelate to Sn(IV) through S and one O atoms. The metal centre is also coordinated by two dimethyl sulfoxide (DMSO) ligands through the O atom, leading to an overall distorted octahedral coordination environment for the Sn(IV) atom. The mol-ecular adduct lies on a twofold rotation axis.
متن کامل(Dimethyl sulfoxide-κO)trimethyl(2-methyl-3,5-dinitrobenzoato-κO 1)tin(IV)
In the title mononuclear complex, [Sn(CH(3))(3)(C(7)H(5)N(2)O(6))(C(2)H(6)OS)], the Sn(IV) ion is coordinated by three methyl groups in the equatorial plane, and by an O atom from a 2-methyl-3,5-dinitrobenzoate ligand and a dimethyl sulfoxide ligand in the axial sites, to form a slightly distorted trigonal-bipyramidal environment. The O atoms of one of the nitro groups are disordered over two s...
متن کامل(Benzyl phenyl sulfoxide-κO)dichloridodiphenyltin(IV)
The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(13)H(12)OS)], displays a distorted C(2)Cl(2)O trigonal-bipyramidal coordination environment, with a mean Sn-C distance of 2.121 (9) Å and with Sn-O = 2.331 (2) Å. The Sn(IV) atom is displaced by 0.169 (2) Å from the equatorial C(2)Cl plane towards the direction of the second axially bonded Cl atom.
متن کامل(Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ2 S 4,S 5)tin(IV)
The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(3)S(5))(C(2)H(6)OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiol-ate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide mol-ecule. In this description, one of the S atoms and the O occupy axial positions. In the crystal, centr...
متن کاملtrans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC 1)tin(IV): crystal structure and Hirshfeld surface analysis
The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl a...
متن کامل